Computer Science
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confemh10r&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Computer Science
Mini-Symposium: Metal Containing Molecules
Scientific paper
Over the last 25 years, organometallic chemistry of f elements has attracted considerable attentions of both experimentalists and theoreticians. We have recently succeeded in producing Ln-benzene (Ln = Lu, Gd) complexes in laser-vaporization supersonic molecular beams and in measuring their vibronic spectra using single-photon pulsed field ionization-zero electron kinetic energy (PFI-ZEKE) spectroscopy. We obtained for the first time the adiabatic ionization energy (AIE) and metal-benzene vibrational frequencies. The AIE of the Lu-benzene complex is 44461 (5) cm-1, and the Lu-benzene stretching frequencies are 204 and 270 cm-1 in the neutral and ion, respectively. For the Gd-benzene complex, its AIE is 40830 (5) cm-1, and the metal-ligand stretching frequencies of the neutral and ionic species are 256 and 298 cm-1. We will discuss the electronic transitions involved in the PFI-ZEKE spectra of the two complexes by combining the experimental measurements with quantum chemical calculations and spectral simulations.
Kumari Sudesh
Roudjane Mourad
Yang Dong-Sheng
No associations
LandOfFree
Pulsed-Field Ionozation Electron Spectroscopy of Lanthanide (Lu, Gd) Benzene Complexes does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Pulsed-Field Ionozation Electron Spectroscopy of Lanthanide (Lu, Gd) Benzene Complexes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Pulsed-Field Ionozation Electron Spectroscopy of Lanthanide (Lu, Gd) Benzene Complexes will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1591004