Integrated Absorbances in the 3.4 Micron CHn Band in Hydrogenated Amorphous Carbon

Astronomy and Astrophysics – Astronomy

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Infrared: Ism: Lines And Bands, Ism: Dust, Extinction

Scientific paper

We have measured the integrated absorbance, A (in units of cm molecule ^{-1} ), for the spectral components of the 3.4 mu m CHn absorption band in hydrogenated amorphous carbon (HAC) for samples deposited at 300 and 77 K. For the asymmetric CH3 stretching band in HAC, A is found to be significantly weaker than that occurring in pure saturated aliphatic hydrocarbons, while the symmetric mode of this group has a comparable intensity in HAC and in pure hydrocarbons. This suggests that the relative strength of CH3 symmetric and asymmetric absorption components may be a useful diagnostic of CH3 bonding in interstellar carbonaceous materials. Our measured absorbances, together with observed optical depths in the 3.4 mu m absorption band in the diffuse interstellar medium, suggest that N(C)/N(H) ~ 72-97 parts per million in HAC in diffuse clouds. We discuss the possibility that aromatic carbon particles with CHn edge and defect groups may be the source of both the 2175 A extinction bump and the 3.4 mu m CHn absorption band.

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