Computer Science
Scientific paper
Aug 1968
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1968gecoa..32..853h&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 32, Issue 8, pp.853-877
Computer Science
28
Scientific paper
Application of the thermodynamic principles of chemical petrology and solution chemistry to the study of geochemical processes permits prediction of the consequences of reaction between aqueous solutions of electrolytes and typical igneous, metamorphic, and sedimentary mineral assemblages. A given geochemical process can be represented by a set of reversible and irreversible chemical reactions that corresponds to an array of linear differential equations relating partial equilibrium and nonequilibrium in thermodynamic systems. Simultaneous evaluation of these equations defines the nature and extent of the compositional change and redistribution of species in the aqueous phase, the order of appearance of stable and metastable phases, and the mass transfer resulting from irreversible reactions between the minerals and the aqueous solution.
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