Hydrated Silica at Mawrth Vallis and Implications for Past Environment

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[5410] Planetary Sciences: Solid Surface Planets / Composition, [5464] Planetary Sciences: Solid Surface Planets / Remote Sensing, [6225] Planetary Sciences: Solar System Objects / Mars

Scientific paper

Hydrated silica has been identified in many outcrops in the Mawrth Vallis region [1-3] often mixed with Al-bearing phyllosilicates such as kaolinite and montmorillonite. To determine which form of hydrated silica could be mixed with the Al-phyllosilicates at Mawrth Vallis, spectra of intimate mineral mixtures were measured in the lab and compared to CRISM spectra (figure 1). The mixtures considered were: kaolinite-opal-A, kaolinite-montmorillonite, montmorillonite-obsidian, montmorillonite-hydrated silica (opal), and glass-illite-smectite. The best spectral matches with Martian data from our lab experiments are mixtures of montmorillonite and obsidian having 20 to 50 % montmorillonite or mixtures of kaolinite and montmorillonite with 25 to 50 % kaolinite. The spectra of clay mixtures with opal and of hydrothermally altered glass-illite-smectite did not represent as well the Martian spectra observed in this region. This suggests that a cryptocrystalline (obsidian) or crystalline form of hydrated silica is present at Mawrth Vallis rather than an amorphous form (opal-A) which has been identified elsewhere on Mars [e.g. 4]. References: [1] Bishop, J. L. et al. (2008) Science, 321, 830-833. [2] McKeown, N. K. et al. (2009) JGR- Planets, 114, E00D10. [3] Noe Dobrea, E. Z. et al. (2010) JGR- Planets, 115, E00D19. [4] Milliken, R. E. et al. (2008) Geology, 36, 847-850. Figure 1 (left) Spectra of montmorillonite-obsidian mixtures compared to CRISM spectra from FRT0000848D. (right) Spectra of kaolinite-montmorillonite and kaolinite-SiOH (opal-A) mixtures compared to CRISM spectra from HRL000043EC and FRT0000848D.

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