Intensities and broadening coefficients for the Q branch of the 4nu-2 - nu-1 + nu-2 (471.511/cm) band of CO2

Computer Science

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Carbon Dioxide, Laser Spectroscopy, Spectral Line Width, Nitrogen, Oxygen, Semiconductor Lasers, Spectral Bands, Tunable Lasers

Scientific paper

Absolute intensities for the Q-branch of the 4nu-2 - nu-1 + nu-1/2 (20,003-11,101) band in CO2 were measured for the first time. Measurements were performed for lines Q10 to Q28, at temperatures ranging from 385 to 426 K, for pressures from 3 to 40 torr, using our long wavelength tunable diode laser spectrometer. The combination of tunable diode lasers, a White cell, and a blocked impurity band detector made it possible to obtain signal to noise ratios greater than 1000 in the 471/cm spectral region, with about 3 x 10 exp -4/cm spectral resolution. The band strength was found to be 8.6(2) x 10 exp -25 cm/molec at 296 K, and the Hermann-Wallis factor was determined. Comparison with the values listed in the HITRAN 92 data base are presented. Self-, N2- and O2-broadening coefficients were also measured.

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