New insight in tholin chemical structure through 13C and 15N solid state nuclear magnetic resonance

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Tholins are complex materials synthesized in laboratory as models of the molecules occurring in the atmosphere of Titan. Using labeled gases, pure 13C and 15N-enriched tholins were synthesized and analyzed using 13C and 15N nuclear magnetic resonance. This study allowed confirming the presence of some functional groups (cyano, amino, imino) previously inferred from other techniques and to assess their relative contribution. It also indicated that some other functions (such as carbodiimide, protonated aromatic carbons) if present, only show a very low contribution and ruled out the occurrence of hydrazones.

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