Heats of Formation of Mercury Dimethyl, Diethyl and Diphenyl and some Associated Bond Dissociation Energies

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Scientific paper

THE values obtained by Berthelot1 for the heats of formation of some of the organic compounds of mercury have been in doubt for some time. A re-examination of these compounds is especially important, since their heats of formation can be combined with other recent thermochemical data to give the mean bond energy of the C-Hg bond and the heats of formation of various alkyl and aryl halides. The values for the halides throw considerable light on C-halogen bond dissociation energies and the C-H dissociation energy in benzene.

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