Identification of 4- to 7-quantum v3 bands in the atmospheric recombination spectrum of ozone

Details Identification of 4- to 7-quantum v3 bands in the atmospheric recombination spectrum of ozone Identification of 4- to 7-quantum v3 bands in the atmospheric recombination spectrum of ozone

Sep 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990p%26ss...38.1121a&link_type=abstract

Planetary and Space Science (ISSN 0032-0633), vol. 38, Sept. 1990, p. 1121-1132. Research supported by DNA.

Computer Science

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14

Atmospheric Radiation, Chemiluminescence, Emission Spectra, Ozone, Spectral Bands, Vibrational Spectra, Michelson Interferometers, Rocket Sounding

Scientific paper

Spectra of ozone hot band chemiluminescence obtained in the SPIRIT 1 rocket experiment have been analyzed with the aid of laboratory data and vibrational energy and band contour predictions. Band centers and energies for previously unreported vibrational states of ozone having up to seven quanta have been derived. The assignments are supported by the predictions of an improved Darling-Dennison-type energy level formula which behaves realistically toward dissociation. Bands associated with bending as well as stretching excitation appear due to an accidental vibrational resonance and a nonmode-specific population distribution.

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