Equilibrium Chemistry of the Atmospheres of Scorched Rocky Exoplanets

Statistics – Computation

Scientific paper

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Scientific paper

The Kepler and COROT missions and Earth-based observations detected putative rocky exoplanets. Some of the planets are exposed to extreme temperatures as they orbit close to their host stars, e.g., CoRot-7b. Such planets can develop atmospheres through (partial) vaporization of their exterior crusts or even mantle silicates. We investigated the chemical equilibrium composition of such heated systems from 500 - 4000 K and total pressures from 10-6 to 10+2.5 bars. The major gas phase species formed by the volatile elements H, C, N, O, and S, and the lithophile elements Na, K, Fe, Si, Mg, Al, Ca, and Ti are H2O and CO2 at low temperatures, and Na, K, O2, SiO, and O at high temperatures. The effects on overall elemental composition of the evaporated systems will be discussed. The computational results will be useful in planning spectroscopic studies of the atmospheres of hot Earth-like exoplanets. This work was supported by the NSF Astronomy Program and the NASA Astrobiology Program.

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