Soluble inorganic ferrous complexes in natural waters

Details Soluble inorganic ferrous complexes in natural waters Soluble inorganic ferrous complexes in natural waters

Oct 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979gecoa..43.1693d&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 43, Issue 10, pp.1693-1696

Computer Science

5

Scientific paper

Recent stability constant data for ferrous complexation by chloride, hydroxide and sulphate ions are used to recalculate the equilibrium distribution of soluble ferrous species at pH 7 and 8 in fresh- and seawater. Contrary to previous calculations hydroxy complexes are negligible and the aquated Fe 2+ ion is the dominant species for all conditions. In seawater up to 15% of the iron might be present as chloride complexes, and 9% as sulfate complexes. The implications of these results to mineral formation are discussed.

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