Statistical Model For H++D2 Reactive Collisions Based On Mean Isotropic Interaction Potential

Astronomy and Astrophysics – Astronomy

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The reactive collision process H++D2(v= 0, j= 0) ?HD +D+, for collision energies ranging from the threshold to 1.3 eV, is studied by using a statistical theory based on a mean isotropic potential deduced from a full potential energy surface. Calculated integral cross sections are compared with recent statistical and quantum mechanical calculations performed by using a full potential energy surface. Reasonable agreement between the results obtained by using the two statistical methods is found, both of which however, overestimate quantum mechanical predictions.

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