Fourier-transform infrared dichroism investigation of molecular orientation in elastomeric networks

Details Fourier-transform infrared dichroism investigation of molecular orientation in elastomeric networks Fourier-transform infrared dichroism investigation of molecular orientation in elastomeric networks

Jun 1998

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998aipc..430..531b&link_type=abstract

The eleventh international conference on fourier transform spectroscopy. AIP Conference Proceedings, Volume 430, pp. 531-534 (1

Computer Science

Organic Compounds, Polymers, Infrared Spectrometers, Auxiliary Equipment, And Techniques

Scientific paper

Segmental orientation in uniaxially stretched poly(dimethylsiloxane) (PDMS) elastomeric networks is investigated by Fourier-transform infrared dichroism. Precise determination of the dichroic effects, in the mid- as well as in the near-infrared range, are obtained by polarization modulation of the incident electromagnetic field. Introduction of reinforcing filler such as silica in PDMS leads to an increase in orientation, attributed to the additional cross-links produced by the filler.

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