Vibrational transition probabilities, r-bar-centroids and Morse PE-curves for MgO

Astronomy and Astrophysics – Astrophysics

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Centroids, Magnesium Oxides, Solar Spectra, Transition Probabilities, Vibrational Spectra, Atomic Energy Levels, Franck-Condon Principle, Morse Potential, Potential Energy, Quantum Numbers

Scientific paper

Vibrational transition probabilities (namely, Franck-Condon factors and r-bar-centroids) have been evaluated using an approximate analytical method for the B-A system of MgO. Morse potential energy (PE) curves for B 1Sigma(+) and A 1Pi states of MgO have been constructed by use of the latest spectroscopic data. The values of r-bar-centroids for the band have been found to decrease linearly with the corresponding wavelength. Results for six new bands in the umbral spectrum of the sun are given.

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