Integrated band intensities in N2O4 in the infrared range

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Atmospheric Chemistry, Infrared Radiation, Nitrogen Oxides, Spectral Bands, Stratosphere, Temperature Dependence, Atmospheric Composition, Molecules, Spectrum Analysis, Thermodynamics

Scientific paper

We have measured the integrated band intensities of the nu(sub 9) and nu(sub 11) bands of N2O4 which are observed around 1757 and 1261/cm, respectively. By varying temperature and pressure, we have obtained: S(sub band)(nu (sub 9)) = 9.60(130), 9.10(24), 8.80(66) and S(sub band)(nu(sub 11)) = 5.93(64), 5.70(21) and 5.33(46) (in 10(exp -17) cm/molecule) at 293.15 (60), 277.25 (60) and 261.65 (60) K, respectively.

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