Lepidocrocite to maghemite to hematite: A pathway to have magnetic and hematitic Martian soil

Other

Scientific paper

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

13

Scientific paper

We examined decomposition products of lepidocrocite, which were produced by heating the phase in air at temperatures up to 525(C for 3 and 300 hr, by XRD, TEM, magnetic methods, and reflectance spectroscopy (visible and near-IR). Single-crystal lepidocrocite particles dehydroxylated to polycrystalline particles of disordered maghemite which subsequently transformed to polycrystalline particles of hematite. Essentially pure maghemite was obtained at 265 and 223(C for the 3 and 300 hr heating experiments, respectively. Its saturation magnetization (Js) and mass specific susceptibility are ~50 Am2/kg and ~400 x 10-6 m3/kg, respectively. Because hematite is spectrally dominant, spectrally-hematitic samples (i.e., a minimum near 860 nm and a maximum near 750 nm) could also be strongly magnetic (Js up to ~30 Am2/kg) from the masked maghemite component. TEM analyses showed that individual particles are polycrystalline with respect to both maghemite and hematite. The spectrally-hematitic and magnetic Mh+Hm particles can satisfy the spectral and magnetic constraints for Martian surface materials over a wide range of values of Mh/(Mh+Hm) either as pure oxide powders or (within limits) as components of multiphase particles. These experiments are consistent with lepidocrocite as the precursor of Mh+Hm assemblages on Mars, but other phases (e.g., magnetite) that decompose to Mh and Hm are also possible precursors. Simulations done with a copy of the Mars Pathfinder Magnet Array showed that spectrally hematitic Mh+Hm powders having Js equal to 20.6 Am2/kg adhered to all five magnets.

No associations

LandOfFree

Say what you really think

Search LandOfFree.com for scientists and scientific papers. Rate them and share your experience with other people.

Rating

Lepidocrocite to maghemite to hematite: A pathway to have magnetic and hematitic Martian soil does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Lepidocrocite to maghemite to hematite: A pathway to have magnetic and hematitic Martian soil, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Lepidocrocite to maghemite to hematite: A pathway to have magnetic and hematitic Martian soil will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFWR-SCP-O-1268797

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.