The aqueous geochemistry of rare earth elements: V. Application of photoacoustic spectroscopy to speciation at low rare earth element concentrations

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Photoacoustic spectroscopy (PAS) yields information on complexation identical to that obtainable with conventional UV-visible absorption spectroscopy, but is up to three orders of magnitude more sensitive. The applicability of PAS to the study of Er 3+ oxalate and hydroxide complexes, at 25°C and 1 bar, has been demonstrated. Spectra can be obtained at concentrations as low as 10-20 M, and observed spectral changes as a function of pH and oxalate concentration are consistent with the most reliable thermodynamic data available for these systems.

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