Distribution of solutes between coexisting steam and water

Details Distribution of solutes between coexisting steam and water Distribution of solutes between coexisting steam and water

Jul 1994

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994gecoa..58.2789a&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 58, Issue 13, pp.2789-2798

Computer Science

5

Scientific paper

For a thorough description of aqueous systems with coexisting liquid-vapor phases, it is necessary to have a means of describing the concentration of solutes in the two-fluid phases over a wide temperature range. A general procedure is presented which allows the description of the distribution ratio of solutes at infinite dilution ( K D ) between water and steam over all the range of coexistence of the two-fluid phases. The procedure has been employed for many different solutes, e.g., nonreactive gases, reactive gases, nonionic, and ionic solutes. For the gaseous solutes a formulation is given which allows the calculation of K D over the complete temperature range with good precision

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