Effects of collisional narrowing and line parameters on atmospheric composition measurements

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Atmospheric Composition, Line Shape, Molecular Spectroscopy, Spectral Line Width, Stratosphere, Atmospheric Radiation, High Resolution, Spectral Resolution, Temperature Dependence

Scientific paper

The effects of line shape and of line width and its temperature dependence on retrieved stratospheric composition from ground-based, high-resolution solar spectra measurements are discussed. The results show that they depend on the method of measurement. For differential transmission measurements, large effects of line-shape and other line parameters are found. Even for transmission measurements, line parameters can also lead to significant error.

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