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Scientific paper
Jul 1992
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992metic..27r.260m&link_type=abstract
Meteoritics, vol. 27, no. 3, volume 27, page 260
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1
Scientific paper
Turekian (1982) propagated the use of the osmium isotopic composition as a cosmic indicator for the origin of the high osmium (and iridium) layers at the K/T boundaries. He did not consider the osmium isotopic signature of the terrestrial mantle, which also has a chondritic evolution of the Re-Os system. Osmium cannot serve alone as an infallible indicator of the impact theory, but interesting results can be obtained from their investigation. Different K/T boundary section have been analyzed so far for ^187Os/^186Os. An overview of the values is presented in the table. Boundary Clay layer Os ratio Reference Stevns Klint fish clay 1.66 Luck and Turekian, 1983 Woodside Creek 1.12 Lichte et al., 1986 Raton Basin 1.23 Kraehenbuehl et al., 1988 Raton Basin (several) 1.15-1.23 Esser and Turekian, 1989 Sumbar (0-1 cm) 1.16 This work We obtained a complete marine section of the K/T boundary in southern Turkmenia (decribed by Alekseyev, 1988). It shows a very high Ir concentration (66 ppb) at the boundary layer and a remarkable Ir enrichment over crustal rocks continuing up to 30 cm above the boundary. Our aim of this investigation is to analyze several samples from above and below the boundary for the ^187Os/^186Os ratio to obtain a complete picture of the isotopic evolution of the section. We want to evaluate mixing of Os with chondritic ratios with Os from upper crustal rocks. Another goal is to investigate a mobilization of Os. So far only one sample has been analyzed with NTI-MS after fire assay digestion of the sample. The sample 0 to 1 cm has an ^187Os/^186Os ratio of 1.162 +- 13, which is quite low. We expect an even lower value for the boundary clay (0 cm) itself not taking into account a contribution of radiogenic osmium from the decay of terrestrial rhenium. This might put this K/T boundary section closest of all to the present day chondritic value (approx. 1.05). Further analysis will be presented at the meeting. References Alekseyev A. S., Nazarov M. A., Barsukova L. D., Koselov G. M., Nizhegorodova I. V. and Amanniyazov K. N. (1988) The Cretaceous- Paleogene boundary in southern Turkmenia and its geochemical characteristics. Int. Geol. Rev. 30, 121-135. Esser B. K. and Turekian K. K. (1989) Osmium isotopic composition of the Raton Basin Cretaceous-Tertiary boundary interval. 70, 717. Kraehenbuehl U., Geissbuehler M., Buehler F. and Eberhardt P. (1988) The measurement of osmium isotopes in samples from a Cretaceous/Tertiary (K/T) section of the Raton Basin, USA. Meteoritics 23, 282. Lichte F. E., Wilson S. M., Brooks R. R., Reeves R. D., Holzbecher J. and Ryan D. E. (1986) New method for the measurement of osmium isotopes applied to a New Zealand Cretaceous/Tertiary boundary shale. Nature 322, 816-817. Luck J. M. and Turekian K. K. (1983) Osmium-^187/Osmium-^186 in manganese nodules and the Cretaceous-Tertiary boundary. Science 222, 613- 615. Turekian K. K. (1982) Potential of ^187Os/^186Os as a cosmic versus terrestrial indicator in high iridium layers of sedimentary strata. Geol. Bull. Am. Spec. Pap. 190, 243-249.
Krähenbühl Urs
Meisel Th.
Nazarov Michael A.
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