Astronomy and Astrophysics – Astrophysics
Scientific paper
Apr 2001
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2001a%26a...369..611s&link_type=abstract
Astronomy and Astrophysics, v.369, p.611-615 (2001)
Astronomy and Astrophysics
Astrophysics
11
Ism: Abundances, Ism: Molecules
Scientific paper
Using quantum chemical and kinetic techniques, we show that the reaction between two HCN molecules under interstellar conditions cannot lead efficiently to a dimer of this species (H2C2N2), whatever its structure. If the dimerization reaction does not occur efficiently, then it is impossible to synthesize detectable abundances of the pre-biotic HCN oligomer adenine (H5C5N5) in the interstellar medium via successive neutral-neutral reactions between HCN and its dimer, trimer, and tetramer.
Herbst Eric
Smith Ian W. M.
Talbi Dahbia
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