The production of HCN dimer and more complex oligomers in dense interstellar clouds

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Ism: Abundances, Ism: Molecules

Scientific paper

Using quantum chemical and kinetic techniques, we show that the reaction between two HCN molecules under interstellar conditions cannot lead efficiently to a dimer of this species (H2C2N2), whatever its structure. If the dimerization reaction does not occur efficiently, then it is impossible to synthesize detectable abundances of the pre-biotic HCN oligomer adenine (H5C5N5) in the interstellar medium via successive neutral-neutral reactions between HCN and its dimer, trimer, and tetramer.

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