The ion-molecule chemistry of acrylonitrile - Astrochemical implications

Astronomy and Astrophysics – Astronomy

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Acrylonitriles, Interstellar Chemistry, Molecular Clouds, Molecular Ions, Stellar Models, Carbon Monoxide, Hydrogen, Nitrogen, Reaction Kinetics

Scientific paper

This paper reports the results of laboratory measurements of ion-molecule reactions of ions derived from acrylonitrile, CH2CHCN, namely C3HnN(+) (n = 1-4), as well as of measurements involving ions of relevance to the interstellar cloud chemistry of CH2CHCN. Sources and sinks for CH2CHCN proposed in recent models have been reexamined in the light of these measurements. Most ions relevant to cloud chemistry undergo collision-rate reactions with CH2CHCN but the C3HnN(+) ions are relatively unreactive with most important neutral constituents of clouds including H2, CO, and N2.

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