Zr/Rb ratio in the Chinese loess sequences and its implication for changes in the East Asian winter monsoon strength

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The long-term dust accumulation sequences on the Chinese Loess Plateau (CLP) provide a valuable opportunity to study the evolution of East Asian winter monsoon strength. Grain size of bulk samples of loess deposits, though widely used, is a modified measure of the strength of winter monsoon wind due to modification by post-depositional weathering and pedogenesis. This study proposes a new and reliable geochemical climate proxy that records the variability of the East Asian winter monsoon on the CLP. Six loess paleosol sections on the Plateau were selected for measuring concentrations of the trace elements Zr and Rb as well as grain size. Variations of the Zr/Rb ratio in all the sections encompassing the last 130 ka display a generally similar pattern to that of mean grain size of bulk samples (MGSB). Though a positive correlation exists between the Zr/Rb ratio and MGSB, the correlation coefficient decreases in southern and eastern sections where intense pedogenesis occurred in the relatively warm and humid climates. Long-term Zr/Rb variation in the Lingtai section exhibits amplitudes and frequencies similar to those in MGSB and the mean grain size of quartz particles (MGSQ, accepted as a more reliable proxy than MGSB) in the upper loess paleosol sequence over the past 2.6 Ma. However, for the underlying Red Clay formation, in the interval from about 7 2.6 Ma B.P., the MGSB record is relatively stable, whereas both the Zr/Rb ratio and MGSQ show distinct variability and display amplitudes similar to those observed in the overlying loess paleosol sequence. These results demonstrate that the Zr/Rb ratio reflects original eolian grain size and may serve as a reliable index of the strength of East Asian winter monsoon winds.

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