The A^3Phi-X^3Delta System (gamma Bands) of TIO: Laboratory and Sunspot Measurements

Astronomy and Astrophysics – Astronomy

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Line Identification, Methods: Laboratory, Molecular Data, Sun: Sunspots

Scientific paper

The spectrum of the A^3Phi-X^3Delta system of TiO has been measured in the laboratory as well as in sunspots. In the laboratory, the bands were excited in a hollow cathode lamp and were observed using a Fourier transform spectrometer. These bands were also identified in the spectrum of a sunspot umbra recorded with the same spectrometer. Both laboratory and solar measurements have been combined with jet-cooled laser measurements and pure rotational frequencies in the X^3Delta ground state to obtain improved molecular constants for the A^3Phi and X^3Delta states of TiO. RKR potential energy curves and Franck-Condon factors were also calculated.

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