Deuterium Fractionation in Interstellar Clouds: the Influence of Dissociative Recombination of {H_3}(+) and H_2D(+) Ions

Astronomy and Astrophysics – Astronomy

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Scientific paper

The theory of the deuterium fractionation of Dalgarno and Lepp (1984) is extended to include rapid dissociative recombinations of {H_3}(+) and H_2D(+) with electrons. Observational data of molecular ions can be used in conjunction with the theory to derive fractional ionization and abundance of D atoms in cold clouds. In a sample of five clouds upper limits of fractional ionization from 1.8 times 10(-8) to 4.0 times 10(-7) were obtained. Estimates of abundance of atomic deuterium depend on accepted rate coefficient, alpha , for the dissociative recombination {H_3}(+) and H_2D(+) . Assuming alpha < 1.7 times 10(-7) (for T = 273K) we find in the same sample, that the upper limits of fractional abundance of D atoms lie between 3.4 times 10(-7) and 2.0 times 10(-5) .

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