Absorption oscillator strengths for vibration-rotation transitions of ground-state CO

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Carbon Monoxide, Ground State, Infrared Spectra, Molecular Rotation, Transition Probabilities, Vibrational Spectra, Dipole Moments, Electron Transitions, Molecular Energy Levels, Tables (Data)

Scientific paper

Absorption oscillator strengths for IR vibration-rotation bands of CO in the ground electronic state are computed, using the theoretical dipole-moment function of Kirby-Docken and Liu (1977), for rotational quantum numbers (J) up to 110 and vibrational quantum numbers (v) up to 30. Calculated transition oscillator strengths and transition energies are tabulated for the fundamental and first- and second-overtone transitions for J in the range from 0 to 110. A sample assortment of transitions and oscillator strengths is also provided concerning delta v = 4 transitions among highly excited vibrational and rotational levels, which are found to have line strengths comparable to those determined for second-overtone transitions for low values of J-double prime and v-double prime = 0 or 1. The accuracy of the theoretical results is discussed.

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