Thermal stability of hydrocarbons in nature - Limits, evidence, characteristics, and possible controls

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Chemical Composition, Crude Oil, Geochemistry, Hydrocarbons, Thermal Stability, Metamorphism (Geology), Paraffins, Pyrolysis

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Accepted petroleum-geochemical paradigms place rigid limits on hydrocarbon (HC) thermal stability: C(15+) HCs begin thermal cracking at R(0) values of 0.9 and are completely thermally destroyed by R(0) = 1.35 percent; C2-C4 HC gases are thermally destroyed by R(0) = 2.0 percent; and methane is thermally destroyed by R(0) = 4.0 percent. The fact that observed data is so far removed from predicted behavior may be due to: a lack of recognition of some important possible controlling parameters of organic matter metamorphism and too much imporance given to other assumed controlling parameters; and assigning HC distribution patterns in petroleum basins to HC thermal cracking when such patterns may be due to other causes.

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