Some aspects of the stratospheric Cl-ClO-Cl cycle - Possible roles of ClO, ClNO3 and HOCl

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Air Pollution, Atmospheric Chemistry, Chlorine Compounds, Ozone, Stratosphere, Chemical Reactions, Chlorine Oxides, Hydrogen Compounds, Nitrogen Dioxide, Photodissociation, Radiative Lifetime

Scientific paper

The possible inhibitory effect of excited ClO produced during chlorine-sensitized ozone decomposition on the stratospheric Cl-ClO-Cl cycle is investigated. Collisional deactivation of excited ClO is discussed, chemical reactions involving excited ClO are examined, and the possible roles of HO2 and NO2 in weakening the Cl-ClO-Cl cycle are evaluated. It is noted that the formation of HOCl through a reaction between ClO and HO2 implies that the Cl-ClO-Cl cycle has not been completed.

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