Sodium chemistry - A brief review and two new mechanisms for sudden sodium layers

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Aeronomy, Atmospheric Chemistry, Metal Ions, Nightglow, Oxygen Ions, Sodium, Vertical Distribution, Annual Variations, Diurnal Variations, Layers, Mesosphere, Upper Atmosphere

Scientific paper

Two new mechanisms for the formation of sudden sodium layers (SSLs) are tentatively proposed here. One involves ion-ion recombination between coincident layers of Na(+) and O(-) ions formed by e + O2. This reaction, endothermic at room temperatures, may be important during auroras when energetic electrons are present and/or if sufficiently large electric fields are present. A less likely conjecture is that layers of atomic oxygen may mix with layers of sodium compounds to produce SSLs.

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