Measurements of self-broadening of infrared absorption lines of ozone

Computer Science

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Absorption Spectra, Infrared Absorption, Ozone, Rotational Spectra, Spectral Line Width, Vibrational Spectra, Least Squares Method, Quantum Numbers, Spectrometers, Spectrum Analysis

Scientific paper

Lorentz self-broadening coefficients have been determined for 355 spectral lines belonging to five different infrared vibration-rotation bands of O3 in the spectral region from 4.8 to 17 microns. Six ozone absorption spectra, recorded at room temperature using a Fourier transform spectrometer, were analyzed. The half-width values were obtained through a nonlinear least-squares spectral fitting procedure. The results are compared with previous measurements, and the vibration of the half-widths with vibrational and rotational quantum numbers is examined.

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