Ultraviolet absorption cross sections of hydrogen peroxide

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Absorption Cross Sections, Atmospheric Chemistry, Hydrogen Peroxide, Ultraviolet Absorption, Absorption Spectra, Aqueous Solutions, Photodissociation, Spectrophotometry

Scientific paper

Absorption cross-sections of hydrogen peroxide vapor and of neutral aqueous solutions of hydrogen peroxide were measured in the wavelength range from 195 to 350 nm at 296 K. The spectrophotometric procedure is described, and the reported cross-sections are compared with values obtained by other researchers. Photodissociation coefficients of atmospheric H2O2 were calculated for direct absorption of unscattered solar radiation, and the vertical distributions of these coefficients are shown for various solar zenith angles.

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