Exchange of marine sodium for calcium during chemical weathering in the Isle aux Morts River basin, Newfoundland

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Scientific paper

Seasalt corrections applied to major-ion data for the Isle aux Morts River, Newfoundland, using Cl - as the seawater indicator species, produce numerous negative values of Na + that occur chiefly in the winter, when the seasalt concentrations are high. The negative values of Na + are accompanied by slightly higher than usual concentrations of Ca ++ , suggesting an exchange reaction of the form: Ca silicate + 2 Na + = Na 2 silicate + Ca ++ , that is driven by seasalt. That the river receives seasalt inputs of normal major-ion seawater composition is indicated by analysis of precipitation chemistry data for nearby coastal stations.

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