Which isotope effects can be observed in heavy rydberg atoms using resonance ionization mass spectroscopy?

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Multiphoton Ionization And Excitation To Highly Excited States, Mass Spectrometry

Scientific paper

Relative optical isotope shifts are observed in mercury at different energy levels by multiphoton resonance excitation combined with mass spectrometric detection. The sign of isotope shifts changes from negative to positive for states of higher energy. It is negative up to the total excitation energy of Hg[6s(2S)8s 3S1]. It changes to positive for higher energy levels as measured for example in Hg[6s(2S)nd 3D2] with 7<=n<=60. .

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