Vibrational transition probabilities, r(bar)-centroids and Pe-curves for OH and PN

Details Vibrational transition probabilities, r(bar)-centroids and Pe-curves for OH and PN Vibrational transition probabilities, r(bar)-centroids and Pe-curves for OH and PN

Nov 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987ap%26ss.138...79s&link_type=abstract

Astrophysics and Space Science (ISSN 0004-640X), vol. 138, no. 1, Nov. 1987, p. 79-86.

Statistics

Computation

Centroids, Franck-Condon Principle, Transition Probabilities, Vibrational Spectra, Computational Astrophysics, Potential Energy

Scientific paper

Vibrational transition probabilities namely Franck-Condon factors and r-centroids have been evaluated using an approximate analytical method for the A-X systems of OH and PN. KKRV potential energy curves for X2Πi, X1Σ+,A2Σ+, and A1Π states of OH and PN have been constructed using the latest spectroscopic data. The value of r-centroids for the band have been found to increase linearly with the corresponding wavelengths. The author shows results for six new bands and OH and eight new bands of PN in the spectra of astronomical objects.

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