Vibrational transition probabilities, r(bar)-centroids and Morse PE-curves for SiS

Details Vibrational transition probabilities, r(bar)-centroids and Morse PE-curves for SiS Vibrational transition probabilities, r(bar)-centroids and Morse PE-curves for SiS

Dec 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989ap%26ss.162..279s&link_type=abstract

Astrophysics and Space Science (ISSN 0004-640X), vol. 162, no. 2, Dec. 1989, p. 279-285. Research supported by the Council of Sc

Astronomy and Astrophysics

Astrophysics

Centroids, Franck-Condon Principle, Interstellar Matter, Silicon Compounds, Transition Probabilities, Vibrational Spectra, Molecular Clouds, Potential Energy, Quantum Numbers, Sulfides

Scientific paper

Vibrational transition probabilities, namely, Franck-Condon factors and r(bar)-centroids, have been evaluated using an approximate analytical method for the D - X system of SiS. Morse potential energy curves for D1pi and X1 Sigma(+) states of SiS have been constructed using the latest spectroscopic data. The value of r(bar)-centroids for the band have been found to decrease linearly with the corresponding wavelength.

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