Vibration-rotation spectrum of BH X1Σ+ by Fourier transform emission spectroscopy

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Scientific paper

The vibration-rotation emission spectrum of the BH X1Σ+ state was observed with the McMath Fourier transform spectrometer at Kitt Peak. The 1-0, 2-1, and 3-2 bands were observed in a microwave discharge of B2H6 in He. Spectroscopic constants of the individual vibrational levels and equilibrium molecular constants were determined. An RKR potential curve was calculated from the equilibrium constants.
Alfred P. Sloan Fellow; Camille and Henry Dreyfus Teacher-Scholar.

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