Vapor-liquid equilibrium thermodynamics of N2 + CH4 - Model and Titan applications

Details Vapor-liquid equilibrium thermodynamics of N2 + CH4 - Model and Titan applications Vapor-liquid equilibrium thermodynamics of N2 + CH4 - Model and Titan applications

Jun 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992icar...97..187t&link_type=abstract

Icarus (ISSN 0019-1035), vol. 97, no. 2, June 1992, p. 187-199.

Computer Science

44

Liquid-Vapor Equilibrium, Methane, Nitrogen, Phase Transformations, Thermodynamic Equilibrium, Titan, Enthalpy, Henry Law, Latent Heat, Maximum Likelihood Estimates, Raoult Law, Temperature Effects, Troposphere

Scientific paper

A thermodynamic model is presented for vapor-liquid equilibrium in the N2 + CH4 system, which is implicated in calculations of the Titan tropospheric clouds' vapor-liquid equilibrium thermodynamics. This model imposes constraints on the consistency of experimental equilibrium data, and embodies temperature effects by encompassing enthalpy data; it readily calculates the saturation criteria, condensate composition, and latent heat for a given pressure-temperature profile of the Titan atmosphere. The N2 content of condensate is about half of that computed from Raoult's law, and about 30 percent greater than that computed from Henry's law.

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