UV irradiation of hydrogenated amorphous carbon (HAC) as a carrier candidate of the interstellar UV bump at 4.6 μm-1

Astronomy and Astrophysics – Astronomy

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Scientific paper

UV processing of a hydrogenated amorphous carbon (HAC) may provide an interpretation of the interstellar UV bump at 4.6 μm-1 (217.5 nm) in the interstellar extinction curve. Mennella et al. (1996) had found that the UV irradiation of HAC materials has a strong effect creating a new absorption band which appears at 215 nm, attributing this band to %B i-%B i* electronic transitions in clusters of sp^2 hybridized carbon. We have irradiated HAC materials produced by laser ablation in H/He atmospheres with UV doses of up to 33% of the average interstellar dose. Structural investigation by electron microscopy reveals that these materials become more graphitic with UV irradiation. UV spectroscopy of the HACs shows that a stable UV bump appears at around 217 nm, which becomes stronger and narrower with increasing UV dose. The results are compared with the astronomical data of this band.

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