UV absorption cross sections for SO3

Details UV absorption cross sections for SO3 UV absorption cross sections for SO3

Dec 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997georl..24.3201b&link_type=abstract

Geophysical Research Letters, Volume 24, Issue 24, p. 3201-3204

Mathematics

Logic

12

Oceanography: Biological And Chemical: Photochemistry, Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Transmission And Scattering Of Radiation

Scientific paper

Room temperature gas phase absorption cross sections for SO3 have been measured over the wavelength range 195 to 330 nm using a diode array spectrometer. The SO3 spectrum is continuous with weak diffuse vibrational band structure in the 225 to 295 nm region. Atmospheric photolysis rate calculations show that photolysis of SO3 in the 190 to 230 nm actinic window is important in determining the sulfur partitioning in the upper stratosphere.

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