Computer Science
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confetf15l&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Computer Science
Mini-Symposium: Metal Containing Molecules
Scientific paper
A series of complexes of the type [(MM)(piv)_3]_2-μ_2-BL, where M= Mo or W, piv= pivalate, and BL= oxalate or terephthalate, were synthesized. These complexes are known to form strongly coupled mixed valence species in their +1 (singly oxidized) state. Here, we report the properties of the neutral complexes, which are of appropriate symmetry to form mixed valence species in their metal-to-ligand charge transfer (MLCT) excited states. In particular, we discuss the steady state, electroabsorption, and time resolved spectroscopy associated with MLCT excitation. We also consider the inter-relation (if any) of the properties of ground- and excited-state mixed valency.
Bunting Phil C.
Chisholm Malcolm H.
Lear Benjamin J.
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