Transmission electron microscopic study of the immiscibility in natural and synthetic rhyolitic glasses

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Scientific paper

Transmission electron microscopy of nuée ardente scoriae from the Soufrière, St. Vincent, 1979 eruption has revealed the existence of immiscibility at the scale of 300-900 Å. Similar phase separation was reproduced in a synthetic glass with the same composition and the miscibility gap was approximately determined. From these results and the analysis of the natural phase-separated glass, the maximum temperature of the magma prior to the eruption was estimated.
A crude model of the immiscibility, based on Flory's model for polymer solutions, is proposed. It reproduces fairly well the experimentally observed miscibility gap.

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