Toward understanding of H3+ isotopic and nuclear spin fractionations in cold space

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Scientific paper

Two levels of statistical theories describing the H3+ plus H2 system and its isotopic variants at temperatures of astronomical interest (~ 10 K) are presented. The canonical approach accounting for the nuclear spins describes the system in a simple and convenient way. The microcanonical approach based on total energy, total angular momentum and total nuclear spin conservations yields state-to-state details. Non-thermal effects and astronomical implications are discussed.

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