Thermochemical study of the system Fe-As-S

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Scientific paper

The results of and (1964) for the Fe-S system have been combined with a series of new measurements on As-bearing assemblages in the 500°-850°C temperature range to derive data on the free energies, enthalpies, and entropies of formation for arsenopyrite, loellingite, orpiment, realgar, FeAs, and Fe 2 As. The enthalpies and free energies of formation of orpiment and realgar are only approximately one-half as large as indicated in recent compilations of thermochemical data ( et al ., 1965). Data are also presented for the covariation of activity of S 2 (g) with temperature and composition of the sulfur-arsenic liquid.

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