Theoretical study of bound states supported by the I'^1 Pi_g outer potential well in HD

Details Theoretical study of bound states supported by the I'^1 Pi_g outer potential well in HD Theoretical study of bound states supported by the I'^1 Pi_g outer potential well in HD

Jul 2008

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2008pobeo..84..115g&link_type=abstract

Publications of the Astronomical Observatory of Belgrade, vol 84, pp. 115-118

Astronomy and Astrophysics

Astronomy

Scientific paper

The bound states of HD close to the n=2 dissociation limit are strongly affected by non-adiabatic coupling which breaks the gerade-ungerade (g-u) symmetry in HD. The coupled-states formalism is used to describe loosely bound rovibrational states in the I'^1 Pi_g outer potential well. For f -parity states it was sufficient to take into account the constant asymptotic g-u coupling with C^1 Pi_u state. In the case of e -parity states, besides the g-u coupling, the asymptotically strongest rotational coupling with GK^1 Sigma^+_g was also taken into account. The calculated binding energies are in excellent agreement with data obtained in XUV+IR multistep laser experiments.

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