Theoretical photodissociation probability of the CN radical

Details Theoretical photodissociation probability of the CN radical Theoretical photodissociation probability of the CN radical

Jul 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jphb...20.3067l&link_type=abstract

Journal of Physics B - Atomic and Molecular Physics (ISSN 0022-3700), vol. 20, July 14, 1987, p. 3067-3074.

Mathematics

Probability

12

Cyano Compounds, Free Radicals, Interstellar Gas, Photodissociation, Rydberg Series, Self Consistent Fields, Franck-Condon Principle, Oscillator Strengths, Probability Theory, Slater Orbitals

Scientific paper

New SCF-CI calculations of the photodissociation probability of the CN radical both with and without Rydberg functions in the basis set are presented. They have shown that there is no Rydberg state under the interstellar cutoff limit (13.6 eV above the ground state v = 0). A value of 7.4 x 10 to the -10th/s has been determined, which is in close agreement with the interstellar-medium models.

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