The use of principal components analysis for the detection of equilibria and the evaluation of equilibrium constants

Details The use of principal components analysis for the detection of equilibria and the evaluation of equilibrium constants The use of principal components analysis for the detection of equilibria and the evaluation of equilibrium constants

Mar 1977

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1977gecoa..41..387g&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 41, Issue 3, pp.387-392

Computer Science

Scientific paper

A principal components analysis of the chemical potentials of the common participants in a number of chemical interactions may reveal linear combinations of these potentials with variances of close to zero. Each of these combinations defines an equilibrium constant. Application of this method to the results of acid dissolution experiments on montmorillonite revealed an equilibrium between a high-Si derivative of montmorillonite and aluminum ions, hydrogen ions and dissolved silica.

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