The rovibrational intensities of the 2ν3 band of 12C16O18O at 4639 cm-1.

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Carbon Dioxide: Laboratory Spectra, Carbon Dioxide: Infrared Spectra

Scientific paper

The absolute intensities of transitions in the 2ν3 vibrational band of 12C16O18O at 4639.5 cm-1 have been measured in natural isotopic abundance; the spectra were obtained with 0.012 cm-1 resolution using the McMath Fourier transform spectrometer of the National Solar Observatory located at Kitt Peak National Observatory. About 70 transitions have been fitted with an rms deviation of approximately 1.5% to obtain the rotationless band strength of Svib0 = 1.442×10-23 cm molecule-1 at 296 K along with a small first-order Herman-Wallis parameter of A1 = 3.5×10-5; higher order Herman-Wallis parameters could not be determined. The measured line positions, obtained using the CO2 gas samples in the range of 45-65 Torr at room temperature, confirm the current HITRAN tabulated values. The internal precision of the authors' intensity measurements is very high, and the uncertainty due to possible systematic errors is judged to be less than ±3%.

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