The reaction of C(+) with HCN - Isomeric identity of the C2N(+) product

Details The reaction of C(+) with HCN - Isomeric identity of the C2N(+) product The reaction of C(+) with HCN - Isomeric identity of the C2N(+) product

Apr 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986apj...303..439d&link_type=abstract

Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 303, April 1, 1986, p. 439-445. DOE-supported research.

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3

Cyano Compounds, Hydrocyanic Acid, Interstellar Chemistry, Isomers, Molecular Clouds, Reaction Products, Heat Of Formation, Reaction Kinetics

Scientific paper

The determination of kinetic energy release in the present crossed ion beam-molecular beam study of the reaction of C(+) with HCN at relative energies between 0.62 and 1.57 eV furnishes a measure of the energy accessible to the reaction products, and therefore allows a choice to be made between CCN(+) and CNC(+) products (for which both appearance potential measurements and ab initio calculations indicate large heats-of-formation differences). The reaction, whose large exothermicity is consistent only with the production of the stabler CNC(+) isomer, proceeds through the participation of a long lived HCNC(+) complex that decays in a fraction of a rotational period at the highest collision energy. This further confirms that the exothermic channel is the preferred product.

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