The radio spectrum of the C4D radical

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Carbon, Deuterium, Radio Spectra, Acetylene, Chemical Reactions, Electron Transitions, Helium, Line Spectra, Millimeter Waves

Scientific paper

The linear carbon chain radical C4D has been detected in a laboratory discharge through fully deuterated acetylene and helium. Nineteen millimeter-wave rotational transitions from 10 spin-doublets were measured in the frequency range 88 to 282 GHz. The rotational, centrifugal distortion, and spin-rotation parameters were determined with sufficient accuracy to allow the strongest hyperfine components of the N = 1 → 2 and 2 → 3 transitions, those most likely to be detected in a low-temperature source as TMC 1, to be calculated to an equivalent radial velocity of 0.3 km s-1.

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