Computer Science
Scientific paper
Apr 1984
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984gecoa..48..723h&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 48, Issue 4, pp.723-751
Computer Science
42
Scientific paper
The mineral solubility model of and (1980) is extended to the eight component system, Na-K-Mg-Ca-H-Cl-SO 4 -OH-HCO 3 -CO 3 -CO 2 -H 2 O at 25°C to high concentrations. The model is based on the semi-empirical equations of (1973) and co-workers for the thermodynamics of aqueous electrolyte solutions. The model is parameterized using many of the available isopiestic, electromotive force, and solubility data available for many of the subsystems. The predictive abilities of the model are demonstrated by comparison to experimental data in systems more complex than those used in parameterization. The essential features of a chemical model for aqueous electrolyte solutions and the relationship between pH and the equilibrium properties of a solution are discussed.
Harvie Charles E.
Møller Nancy
Weare John H.
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