The photochemistry of methane and carbon monoxide in the troposphere in 1950 and 1985

Computer Science

Scientific paper

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Atmospheric Chemistry, Carbon Monoxide, Methane, Photochemical Reactions, Troposphere, Air Pollution, Atmospheric Composition, Hydroxyl Radicals, Infrared Spectra, Solar Spectra, Spectrum Analysis

Scientific paper

The roughly 1 percent/year increase in tropospheric methane and roughly 2 percent/year increase in tropospheric carbon monoxide deduced from recent analyses of ground-based solar infrared spectra recorded in 1950 and 1951 have very important implications for the photochemistry and chemistry of the troposphere. Photochemical calculations indicate that as a result of the increase of methane and carbon monoxide since 1950-51, levels of the hydroxyl radical, the key species in the photochemistry of the troposphere, may have decreased by about 25 percent.

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